High Nuclearity Uranyl Cages Using Rigid Aryl Phosphonate Ligands
نویسندگان
چکیده
منابع مشابه
Distorted cubic tetranuclear vanadium(IV) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages.
The reaction of VCl(3) with 3,5-dimethylpyrazole (3,5-Me(2)PzH) and trichloromethylphosphonic/tert-butylphosphonic acid in the presence of triethylamine as a hydrogen chloride scavenger afforded the tetranuclear V(IV) assemblies, [(VO)(4)(3,5-Me(2)PzH)(8)(CCl(3)PO(3))(4)] (1) and [(VO)(4)(3,5-Me(2)PzH)(4)(t-BuPO(3))(4)] (2). Both of these compounds possess a distorted cubic framework structures...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2019
ISSN: 1434-1948,1099-0682
DOI: 10.1002/ejic.201900953